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Workshop Series on Advances on Scientific and Engineering Computing (II) —— High Performance Computation: Theory and Applications

Some Numerical Aspects of Langevin Sampling of the Path Integral Molecular Dynamics

Speaker

Zhennan Zhou , Peking University

Time

18 Oct, 14:35 - 15:10

Abstract

We investigate the continuum limit that the number of beads goes to infinity in the ring polymer representation of thermal verages. Studying the continuum limit of the trajectory sampling equation sheds light on possible preconditioning techniques for sampling ring polymer configurations with large number of beads. We propose two preconditioned Langevin sampling dynamics, which are shown to have improved stability and sampling accuracy. We present a careful mode analysis of the preconditioned dynamics and show their connections to the normal mode, the staging coordinate and the Matsubara mode representation for ring polymers. In the case where the potential is quadratic, we show that the continuum limit of the preconditioned mass modified Langevin dynamics converges to its equilibrium exponentially fast, which suggests that the finite-dimensional counterpart has a dimension-independent convergence rate. In addition, the preconditioning techniques can be naturally applied to the multi-level quantum systems in the nonadiabatic regime and the interacting quantum particle systems, which are compatible with various numerical approaches, like the surface hopping method and random batch method.